全文获取类型
收费全文 | 564篇 |
免费 | 31篇 |
国内免费 | 49篇 |
专业分类
化学 | 44篇 |
力学 | 60篇 |
综合类 | 6篇 |
数学 | 161篇 |
物理学 | 373篇 |
出版年
2024年 | 1篇 |
2023年 | 12篇 |
2022年 | 16篇 |
2021年 | 5篇 |
2020年 | 15篇 |
2019年 | 12篇 |
2018年 | 9篇 |
2017年 | 13篇 |
2016年 | 15篇 |
2015年 | 21篇 |
2014年 | 18篇 |
2013年 | 24篇 |
2012年 | 19篇 |
2011年 | 27篇 |
2010年 | 40篇 |
2009年 | 38篇 |
2008年 | 44篇 |
2007年 | 38篇 |
2006年 | 38篇 |
2005年 | 44篇 |
2004年 | 40篇 |
2003年 | 29篇 |
2002年 | 25篇 |
2001年 | 18篇 |
2000年 | 21篇 |
1999年 | 8篇 |
1998年 | 11篇 |
1997年 | 5篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 6篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有644条查询结果,搜索用时 234 毫秒
1.
2.
Self-consistent field theory investigation of directed self-assembly in cylindrical confinement 下载免费PDF全文
3.
This paper proposes a transmission structure of zero forcing (ZF) receiver for uplink cell-free massive multiple-input multiple-output (MIMO) systems with device-to-device (D2D) communications, followed by a rate analysis. We assumed that D2D users (DUEs) can utilize orthogonal radio resources to improve the efficiency of the scarce utilization or repurpose the time–frequency-spectrum resources currently used by the cell-free users (CFUEs). Assuming that the imperfect channel state information (CSI) is realizable, after that, the use-and-forget bounding technique is then used to respectively obtain the closed-form expressions of the CFUEs and DUEs, which provide the lower bounds on the ergodic approximate realizable rate of both communication links. First, we calculate the minimum-mean-square error (MMSE) estimation for all channels. Then, the derived results of the achievable uplink sum rate provide us with a tool that enables us to explain how some important parameters, such as the number of access points (APs)/CFUEs, each AP/CFUE/antenna, and the density of DUEs, affect system performance, highlighting the significance of cooperation between cell-free massive MIMO and D2D communication. 相似文献
4.
《Journal of computational chemistry》2017,38(10):645-658
The computational challenge of fast and reliable transition state and reaction path optimization requires new methodological strategies to maintain low cost, high accuracy, and systematic searching capabilities. The growing string method using internal coordinates has proven to be highly effective for the study of molecular, gas phase reactions, but difficulties in choosing a suitable coordinate system for periodic systems has prevented its use for surface chemistry. New developments are therefore needed, and presented herein, to handle surface reactions which include atoms with large coordination numbers that cannot be treated using standard internal coordinates. The double‐ended and single‐ended growing string methods are implemented using a hybrid coordinate system, then benchmarked for a test set of 43 elementary reactions occurring on surfaces. These results show that the growing string method is at least 45% faster than the widely used climbing image‐nudged elastic band method, which also fails to converge in several of the test cases. Additionally, the surface growing string method has a unique single‐ended search method which can move outward from an initial structure to find the intermediates, transition states, and reaction paths simultaneously. This powerful explorative feature of single ended‐growing string method is demonstrated to uncover, for the first time, the mechanism for atomic layer deposition of TiN on Cu(111) surface. This reaction is found to proceed through multiple hydrogen‐transfer and ligand‐exchange events, while formation of H‐bonds stabilizes intermediates of the reaction. Purging gaseous products out of the reaction environment is the driving force for these reactions. © 2017 Wiley Periodicals, Inc. 相似文献
5.
Irena Zupanič Pajnič Carlo Previderè Tomaž Zupanc Martina Zanon Paolo Fattorini 《Electrophoresis》2022,43(13-14):1521-1530
The recent introduction of polymerase chain reaction (PCR)-massively parallel sequencing (MPS) technologies in forensics has changed the approach to allelic short tandem repeat (STR) typing because sequencing cloned PCR fragments enables alleles with identical molecular weights to be distinguished based on their nucleotide sequences. Therefore, because PCR fidelity mainly depends on template integrity, new technical issues could arise in the interpretation of the results obtained from the degraded samples. In this work, a set of DNA samples degraded in vitro was used to investigate whether PCR-MPS could generate “isometric drop-ins” (IDIs; i.e., molecular products having the same length as the original allele but with a different nucleotide sequence within the repeated units). The Precision ID GlobalFiler NGS STR panel kit was used to analyze 0.5 and 1 ng of mock samples in duplicate tests (for a total of 16 PCR-MPS analyses). As expected, several well-known PCR artifacts (such as allelic dropout, stutters above the threshold) were scored; 95 IDIs with an average occurrence of 5.9 IDIs per test (min: 1, max: 11) were scored as well. In total, IDIs represented one of the most frequent artifacts. The coverage of these IDIs reached up to 981 reads (median: 239 reads), and the ratios with the coverage of the original allele ranged from 0.069 to 7.285 (median: 0.221). In addition, approximately 5.2% of the IDIs showed coverage higher than that of the original allele. Molecular analysis of these artifacts showed that they were generated in 96.8% of cases through a single nucleotide change event, with the C > T transition being the most frequent (85.7%). Thus, in a forensic evaluation of evidence, IDIs may represent an actual issue, particularly when DNA mixtures need to be interpreted because they could mislead the operator regarding the number of contributors. Overall, the molecular features of the IDIs described in this work, as well as the performance of duplicate tests, may be useful tools for managing this new class of artifacts otherwise not detected by capillary electrophoresis technology. 相似文献
6.
Ivan Christov 《International Journal of Non》2009,44(5):511-519
We examine the propagation of shocks and traveling wave phenomena on a one-dimensional string that is executing finite-amplitude, transverse vibrations in a resisting medium. As part of our study, we develop an approach that allows us to describe, albeit approximately, the evolution and propagation of a shock front using analytical methods. In addition, exact traveling wave solutions, one of which involves the Lambert W-function, of the string's equation of motion are determined and analyzed. Lastly, a possible new form of the solution to the linearized problem is presented and extensions and other applications of the present work are briefly discussed. 相似文献
7.
应用密度泛函理论PBE0 方法研究具有分子导线潜在应用的金属串配合物M3(dpa)4Cl2 (1: M=Co, 2: M=Rh, 3: M=Ir; dpa=dipyridylamide)在电场作用下的几何和电子结构. 结果表明: 配合物基态均是二重态. 1和2的M36+金属链形成三中心三电子σ键, 3 中M36+形成三中心四电子σ键且存在弱的δ键. 随金属原子周期数增大其M―M键增强、LUMO与HOMO能隙减小、金属原子的反铁磁耦合减弱以至消失且自旋密度向配体的离域增强. 在Cl4→Cl5 电场作用下, 低电势端的M3-Cl5 键缩短, 高电势端的M2―Cl4 键增长, M―M平均键长略为缩短, M―M键增强, 有利于分子线的电子传递; 分子能量降低, 偶极矩线性增大. 低电势端Cl5的负电荷向高电势端Cl4 转移, 且3 中金属原子的正电荷由高电势端向低电势端的转移较明显, 自旋电子由低电势端向高电势端金属原子移动, 但桥联配体dpa-与M和Cl 所在的分子轴间没有电荷转移. 电场使LUMO与HOMO能隙减小, 有利于分子的电子输运. 随金属原子周期数增大, 电场作用下M―M平均键长变化减小, LUMO、HOMO的能级交错现象减少. 相似文献
8.
We prove the existence and uniqueness of a global solution of a damped quasilineat hyperbolic equatiion. We apply a method based on a special integral inequality, to show that the solution decays exponentially, and to obtain precise estimates of the constants in estimates. 相似文献
9.
Fadhel Al‐Musallam Amin Boumenir 《Mathematical Methods in the Applied Sciences》2014,37(11):1610-1623
We are concerned with the reconstruction of a non‐differentiable acoustic stiffness reactance coefficient of a one‐dimensional hyperbolic equation using the smallest possible number of boundary readings generated by classical initial conditions. To this end, a complete set of spectral data of a string is extracted from either a single or at most two readings of the trace of the solution on the boundary. The sought coefficient is then uniquely recovered by the Krein inverse spectral theory. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
10.
The dynamic string motion, which displacement is unilaterally constrained by the rigid termination condition of an arbitrary geometry has been simulated and analyzed. The treble strings of a grand piano usually terminate at a capo bar, which is situated above the strings. The apex of a V-shaped section of the capo bar defines the end of the speaking length of the strings. A numerical calculation based on the traveling wave solution is proposed for modeling the nonlinearity inducing interactions between the vibrating string and the contact condition at the point of string termination. It was shown that the lossless string vibrates in two distinct vibration regimes. In the beginning the string starts to interact in a nonlinear fashion with the rigid terminator, and the resulting string motion is aperiodic. Consequently, the spectrum of the string motion depends on the amplitude of string vibrations, and its spectral structure changes continuously with the passage of time. The duration of that vibration regime depends on the geometry of the terminator. After some time of aperiodic vibration, the string vibrations settle in a periodic regime where the resulting spectrum remains constant. 相似文献